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| Titel |
Bisulfate – cluster based atmospheric pressure chemical ionization mass spectrometer for high-sensitivity (< 100 ppqV) detection of atmospheric dimethyl amine: proof-of-concept and first ambient data from boreal forest |
| VerfasserIn |
M. Sipilä, N. Sarnela, T. Jokinen, H. Junninen, J. Hakala, M. P. Rissanen, A. Praplan, M. Simon, A. Kürten, F. Bianchi, J. Dommen, J. Curtius, T. Petäjä, D. R. Worsnop |
| Medientyp |
Artikel
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| Sprache |
Englisch
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| ISSN |
1867-1381
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| Digitales Dokument |
URL |
| Erschienen |
In: Atmospheric Measurement Techniques ; 8, no. 10 ; Nr. 8, no. 10 (2015-10-01), S.4001-4011 |
| Datensatznummer |
250116620
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| Publikation (Nr.) |
 copernicus.org/amt-8-4001-2015.pdf |
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| Zusammenfassung |
| Atmospheric amines may play a crucial role in formation of new aerosol
particles via nucleation with sulfuric acid. Recent studies have revealed
that concentrations below 1 pptV can significantly promote nucleation of
sulfuric acid particles. While sulfuric acid detection is relatively
straightforward, no amine measurements to date have been able to reach the
critical sub-pptV concentration range and atmospheric amine concentrations
are in general poorly characterized. In this work we present a
proof-of-concept of an instrument capable of detecting dimethyl amine (DMA)
with concentrations even down to 70 ppqV (parts per quadrillion, 0.07 pptV)
for a 15 min integration time. Detection of ammonia and amines other than
dimethyl amine is discussed. We also report results from the first ambient
measurements performed in spring 2013 at a boreal forest site. While minute
signals above the signal-to-noise ratio that could be attributed to
trimethyl or propyl amine were observed, DMA concentration never exceeded
the detection threshold of ambient measurements (150 ppqV), thereby
questioning, though not excluding, the role of DMA in nucleation at this
location. |
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