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Titel Henry's law constants of polyols
VerfasserIn S. Compernolle, J.-F. Müller
Medientyp Artikel
Sprache Englisch
ISSN 1680-7316
Digitales Dokument URL
Erschienen In: Atmospheric Chemistry and Physics ; 14, no. 23 ; Nr. 14, no. 23 (2014-12-08), S.12815-12837
Datensatznummer 250119210
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/acp-14-12815-2014.pdf
 
Zusammenfassung
Henry's law constants (HLC) are derived for several polyols bearing between 2 and 6 hydroxyl groups, based on literature data for water activity, vapour pressure and/or solubility. While deriving HLC and depending on the case, also infinite dilution activity coefficients (IDACs), solid state vapour pressures or activity coefficient ratios are obtained as intermediate results. An error analysis on the intermediate quantities and the obtained HLC is included. For most compounds, these are the first values reported, while others compare favourably with literature data in most cases. Using these values and those from a previous work (Compernolle and Müller, 2014), an assessment is made on the partitioning of polyols, diacids and hydroxy acids to droplet and aqueous aerosol.
 
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