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Titel |
Trajectory matching of ozonesondes and MOZAIC measurements in the UTLS – Part 2: Application to the global ozonesonde network |
VerfasserIn |
J. Staufer, J. Staehelin, R. Stübi, T. Peter, F. Tummon, V. Thouret |
Medientyp |
Artikel
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Sprache |
Englisch
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ISSN |
1867-1381
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Digitales Dokument |
URL |
Erschienen |
In: Atmospheric Measurement Techniques ; 7, no. 1 ; Nr. 7, no. 1 (2014-01-28), S.241-266 |
Datensatznummer |
250115570
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Publikation (Nr.) |
copernicus.org/amt-7-241-2014.pdf |
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Zusammenfassung |
Both balloon-borne electrochemical ozonesondes and MOZAIC (measurements of
ozone, water vapour, carbon monoxide and nitrogen oxides by in-service Airbus
aircraft) provide very valuable data sets for ozone studies in the upper
troposphere/lower stratosphere (UTLS). Although MOZAIC's highly accurate
UV-photometers are regularly inspected and recalibrated annually, recent
analyses cast some doubt on the long-term stability of their ozone analysers.
To investigate this further, we perform a 16 yr comparison (1994–2009) of
UTLS ozone measurements from balloon-borne ozonesondes and MOZAIC. The
analysis uses fully three-dimensional trajectories computed from ERA-Interim
(European Centre for Medium-Range Weather Forecasts Re-analysis) wind fields
to find matches between the two measurement platforms. Although different
sensor types (Brewer-Mast and Electrochemical Concentration Cell ozonesondes)
were used, most of the 28 launch sites considered show considerable
differences of up to 25% compared to MOZAIC in the mid-1990s, followed
by a systematic tendency to smaller differences of around 5–10% in
subsequent years. The reason for the difference before 1998 remains unclear,
but observations from both sondes and MOZAIC require further examination to
be reliable enough for use in robust long-term trend analyses starting before
1998. According to our analysis, ozonesonde measurements at tropopause
altitudes appear to be rather insensitive to changing the type of the
Electrochemical Concentration Cell ozonesonde, provided the cathode sensing
solution strength remains unchanged. Scoresbysund (Greenland) showed
systematically 5% higher readings after changing from Science Pump
Corporation sondes to ENSCI Corporation sondes, while a 1.0% KI cathode
electrolyte was retained. |
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