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Titel Electronically excited molecular nitrogen and molecular oxygen in the high-latitude upper atmosphere
VerfasserIn A. S. Kirillov
Medientyp Artikel
Sprache Englisch
ISSN 0992-7689
Digitales Dokument URL
Erschienen In: Annales Geophysicae ; 26, no. 5 ; Nr. 26, no. 5 (2008-05-28), S.1159-1169
Datensatznummer 250016090
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/angeo-26-1159-2008.pdf
 
Zusammenfassung
Relative vibrational populations of triplet B3Πg, W3Δ,sub>u, B'3Σu states of N2 and the b1Σg+ state of O2 are calculated for different altitudes of the high-latitude upper atmosphere during auroral electron precipitation. It is shown that collisional processes cause a wavelength shift in the distribution of relative intensities for 1PG Δv=3 sequence of N2. The calculation of relative populations for vibrational levels v=1–5 of the b1Σg+ state in the auroral ionosphere has not given an agreement with experimental results. Preliminary estimation of the contribution of the reaction O2++NO to the production of O2(b1Σg+) on the basis of a quantum-chemical approximation does not allow for an explanation of the observable vibrational population of the b1Σg+ state in the aurora.
 
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