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| Titel |
The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N2-N2, N2-O2, O2-O2 |
| VerfasserIn |
A. S. Kirillov |
| Medientyp |
Artikel
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| Sprache |
Englisch
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| ISSN |
0992-7689
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| Digitales Dokument |
URL |
| Erschienen |
In: Annales Geophysicae ; 26, no. 5 ; Nr. 26, no. 5 (2008-05-28), S.1149-1157 |
| Datensatznummer |
250016089
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| Publikation (Nr.) |
 copernicus.org/angeo-26-1149-2008.pdf |
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| Zusammenfassung |
| Contributions of intermolecular electron energy transfers in the electronic
quenching are calculated for molecular collisions N2(A3Σu+, W3Δu)+N2(X1Σg+,
v=0), N2(A3Σu+)+N2(X1Σg+, v≥0), N2(A3Σu+)+O2(X3Σg−, v=0–2),
O2(a1Δg, b1Σg+)+O2(X3Σg−, v=0–2). The calculation has allowed one to
estimate the product branching ratios. It is shown that there is a
dependence of the calculated rate coefficients on the vibrational excitation of
N2(X1Σg+) and O2(X3Σg−) molecules. In many cases, the calculated rate coefficients
have a good agreement with available experimental data. |
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