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| Titel |
1997–2007 CO trend at the high Alpine site Jungfraujoch: a comparison between NDIR surface in situ and FTIR remote sensing observations |
| VerfasserIn |
B. Dils, J. Cui, S. Henne, E. Mahieu, M. Steinbacher, M. Mazière |
| Medientyp |
Artikel
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| Sprache |
Englisch
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| ISSN |
1680-7316
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| Digitales Dokument |
URL |
| Erschienen |
In: Atmospheric Chemistry and Physics ; 11, no. 13 ; Nr. 11, no. 13 (2011-07-13), S.6735-6748 |
| Datensatznummer |
250009913
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| Publikation (Nr.) |
 copernicus.org/acp-11-6735-2011.pdf |
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| Zusammenfassung |
| Within the atmospheric research community, there is a strong interest in
integrated datasets, combining data from several instrumentations. This
integration is complicated by the different characteristics of the datasets,
inherent to the measurement techniques. Here we have compared two carbon
monoxide time series (1997 till 2007) acquired at the high-Alpine research
station Jungfraujoch (3580 m above sea level), with two well-established
measurement techniques, namely in situ surface concentration measurements
using Non-Dispersive Infrared Absorption technology (NDIR), and ground-based
remote sensing measurements using solar absorption Fourier Transform
Infrared spectrometry (FTIR). The profile information available in the FTIR
signal allowed us to extract an independent layer with a top height of 7.18 km above sea level, appropriate for comparison with our in situ
measurements. We show that, even if both techniques are able to measure free
troposphere CO concentrations, the datasets exhibit marked differences in
their overall trends (−3.21 ± 0.03 ppb year−1 for NDIR vs. −0.8 ± 0.4 ppb year−1
for FTIR). Removing measurements that are polluted by uprising
boundary layer air has a strong impact on the NDIR trend (now −2.62 ± 0.03 ppb year−1),
but its difference with FTIR remains significant. Using the
LAGRANTO trajectory model, we show that both measurement techniques are
influenced by different source regions and therefore are likely subject to
exhibit significant differences in their overall trend behaviour. However
the observation that the NDIR-FTIR trend difference is as significant before
as after 2001 is at odds with available emission databases which claim a
significant Asian CO increase after 2001 only. |
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