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| Titel |
Technical Note: Vapor pressure estimation methods applied to secondary organic aerosol constituents from α-pinene oxidation: an intercomparison study |
| VerfasserIn |
S. Compernolle, K. Ceulemans, J.-F. Müller |
| Medientyp |
Artikel
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| Sprache |
Englisch
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| ISSN |
1680-7316
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| Digitales Dokument |
URL |
| Erschienen |
In: Atmospheric Chemistry and Physics ; 10, no. 13 ; Nr. 10, no. 13 (2010-07-09), S.6271-6282 |
| Datensatznummer |
250008616
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| Publikation (Nr.) |
 copernicus.org/acp-10-6271-2010.pdf |
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| Zusammenfassung |
| We applied and compared seven vapor pressure estimation methods to
the condensable compounds generated in the oxidation of α-pinene, as
described by the state-of-the-art mechanism of the BOREAM model Capouet et al., 2008.
Several of these methods had to be extended in order
to treat functional groups such as hydroperoxides and peroxy acyl
nitrates. Large differences in the estimated vapor pressures are reported,
which will inevitably lead to large differences in aerosol formation
simulations. Cautioning remarks are given for some vapor pressure
estimation methods. |
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