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| Titel |
Hygroscopicity of the submicrometer aerosol at the high-alpine site Jungfraujoch, 3580 m a.s.l., Switzerland |
| VerfasserIn |
S. Sjogren, M. Gysel, E. Weingärtner, M. R. Alfarra, J. Duplissy, J. Cozic, J. Crosier, H. Coe, U. Baltensperger |
| Medientyp |
Artikel
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| Sprache |
Englisch
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| ISSN |
1680-7316
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| Digitales Dokument |
URL |
| Erschienen |
In: Atmospheric Chemistry and Physics ; 8, no. 18 ; Nr. 8, no. 18 (2008-09-30), S.5715-5729 |
| Datensatznummer |
250006395
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| Publikation (Nr.) |
 copernicus.org/acp-8-5715-2008.pdf |
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| Zusammenfassung |
Data from measurements of hygroscopic growth of submicrometer aerosol with a
hygroscopicity tandem differential mobility analyzer (HTDMA) during four
campaigns at the high alpine research station Jungfraujoch, Switzerland, are
presented. The campaigns took place during the years 2000, 2002, 2004 and
2005, each lasting approximately one month. Hygroscopic growth factors
(GF, i.e. the relative change in particle diameter from dry diameter,
D0, to diameter measured at higher relative humidity, RH) are presented
for three distinct air mass types, namely for: 1) free tropospheric winter
conditions, 2) planetary boundary layer influenced air masses (during a
summer period) and 3) Saharan dust events (SDE). The GF values at 85% RH
(D0=100 nm) were 1.40±0.11 and 1.29±0.08 for the first two
situations while for SDE a bimodal GF distribution was often found. No phase
changes were observed when the RH was varied between 10–90%, and the
continuous water uptake could be well described with a single-parameter
empirical model. The frequency distributions of the average hygroscopic
growth factors and the width of the retrieved growth factor distributions
(indicating whether the aerosol is internally or externally mixed) are
presented, which can be used for modeling purposes.
Measurements of size resolved chemical composition were performed with an aerosol
mass spectrometer in parallel to the GF measurements. This made it possible
to estimate the apparent ensemble mean GF of the organics (GForg)
using inverse ZSR (Zdanovskii-Stokes-Robinson) modeling. GForg was found
to be ~1.20 at aw=0.85, which is at the upper end of previous laboratory
and field data though still in agreement with the highly aged and oxidized
nature of the Jungfraujoch aerosol. |
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