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Titel |
Water-side turbulence enhancement of ozone deposition to the ocean |
VerfasserIn |
C. W. Fairall, D. Helmig, L. Ganzeveld, J. Hare |
Medientyp |
Artikel
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Sprache |
Englisch
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ISSN |
1680-7316
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Digitales Dokument |
URL |
Erschienen |
In: Atmospheric Chemistry and Physics ; 7, no. 2 ; Nr. 7, no. 2 (2007-01-25), S.443-451 |
Datensatznummer |
250004469
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Publikation (Nr.) |
copernicus.org/acp-7-443-2007.pdf |
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Zusammenfassung |
A parameterization for the deposition velocity of an ocean-reactive
atmospheric gas (such as ozone) is developed. The parameterization is based
on integration of the turbulent-molecular transport equation (with a
chemical source term) in the ocean. It extends previous work that only
considered reactions within the oceanic molecular sublayer. The sensitivity
of the ocean-side transport to reaction rate and wind forcing is examined. A
more complicated case with a much more reactive thin surfactant layer is
also considered. The full atmosphere-ocean deposition velocity is obtained
by matching boundary conditions at the interface. For an assumed ocean
reaction rate of 103 s−1, the enhancement for ozone deposition by
oceanic turbulence is found to be up to a factor of three for meteorological
data obtained in a recent cruise off the East Coast of the U.S. |
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