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Titel Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
VerfasserIn R. Atkinson
Medientyp Artikel
Sprache Englisch
ISSN 1680-7316
Digitales Dokument URL
Erschienen In: Atmospheric Chemistry and Physics ; 3, no. 6 ; Nr. 3, no. 6 (2003-12-22), S.2233-2307
Datensatznummer 250001354
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/acp-3-2233-2003.pdf
 
Zusammenfassung
The available database concerning rate constants for gas-phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented over the entire temperature range for which measurements have been made (~180-2000 K). Measurements made using relative rate methods are re-evaluated using recent rate data for the reference compound (generally recommendations from this review). In general, whenever more than one study has been carried out over an overlapping temperature range, recommended rate constants or temperature-dependent rate expressions are presented. The recommended 298 K rate constants, temperature-dependent parameters, and temperature ranges over which these recommendations are applicable are listed in Table 1.
 
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