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Titel Controls of evaporative irrigation return flows in comparison to seawater intrusion in coastal karstic aquifers in northern Sri Lanka: evidence from solutes and stable isotopes
VerfasserIn Rohana Chandrajith, Saranga Diyabalanage, Mahinda Premathilake, Christian Hanke, Robert van Geldern, Johannes A. C. Barth
Konferenz EGU General Assembly 2016
Medientyp Artikel
Sprache en
Digitales Dokument PDF
Erschienen In: GRA - Volume 18 (2016)
Datensatznummer 250127616
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2016-7512.pdf
 
Zusammenfassung
Groundwater in Miocene karstic aquifers in the Jaffna Peninsula of Sri Lanka is an important resource since no other fresh water sources are available in the region. The subsurface is characterized by highly productive limestone aquifers that are used for drinking and agriculture purposes. A comprehensive hydrogeochemical study was carried out to reveal the processes affecting the groundwater quality in this region. Major and trace element composition and environmental isotope ratios of oxygen and hydrogen (δ18OH2O and δ2HH2O) were determined in 35 groundwater samples for this investigation. The ion abundance of groundwater in the region was characterized by an anion sequence order with HCO3¯ >Cl¯ >SO4¯ >NO3¯ . For cations, average Na++K+ contents in groundwater exceeded those of Ca2++Mg2+ in most cases. Ionic relationships of major solutes indicated open system calcite dissolution while seawater intrusions are also evident but only close to the coast. The solute contents are enriched by agricultural irrigation returns and associated evaporation. This was confirmed by the stable isotope composition of groundwater that deviated from the local meteoric water line (LMWL) and formed its own regression line denoted as the local evaporation line (LEL). The latter can be described by δ2HH2O=5.8 ×δ18OH2O - 2.9. Increased contents of nitrate (up to 26 mg/L), sulfate (up to 430 mg/L) and fluoride (up to 1.5 mg/L) provided evidences for anthropogenic inputs of solutes, most likely from agriculture activities. Among trace elements Ba, Sr, As and Se levels in the Jaffna groundwater were higher compared to that of the dry zone metamorphic aquifers in Sri Lanka. Solute geochemistry and stable isotope evidences from the region indicates that groundwater in the area is mainly derived from local modern precipitation but modified heavily by progressive evaporative concentration rather than seawater intrusion. The currently most imminent vulnerability of groundwater in the region occurs through anthropogenic pollution, and particularly so due to agricultural activities. Extensive groundwater use in the peninsula may also further add concerns of active seawater intrusion after intense abstraction. The area should remain under close monitoring for both quality and quantity in order to protect groundwater as a vulnerable resource. Reference Chandrajith, R., Diyabalanage, S., Premathilake, K.M., Hanke, C., van Geldern, R. and Barth, J.A.C. (2016): Controls of evaporative irrigation return flows in comparison to seawater intrusion in coastal karstic aquifers in northern Sri Lanka: evidence from solutes and stable isotopes. - Science of the Total Environment, in press, [doi:10.1016/j.scitotenv.2016.01.050].