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Titel An improved method for the determination of dissolved nitric oxide (NO) in seawater samples
VerfasserIn H. E. Lutterbeck, H. W. Bange
Medientyp Artikel
Sprache Englisch
ISSN 1812-0784
Digitales Dokument URL
Erschienen In: Ocean Science ; 11, no. 6 ; Nr. 11, no. 6 (2015-11-27), S.937-946
Datensatznummer 250117330
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/os-11-937-2015.pdf
 
Zusammenfassung
Nitric oxide (NO) is a short-lived intermediate of the oceanic nitrogen cycle; however, due to its high reactivity, measurements of dissolved NO in seawater are rare. Here we present an improved method to determine NO concentrations in discrete seawater samples. The set-up of our system consisted of a chemiluminescence NO analyser connected to a stripping unit. The limit of detection for our method is 5 pmol NO in aqueous solution, which translates into 0.25 nmol L−1 when using a 20 mL seawater sample volume. Our method was applied to measure high-resolution depth profiles of dissolved NO during a cruise to the eastern tropical South Pacific Ocean. It is fast and comparably easy to handle; thus it opens the door for investigating the distribution of NO in the ocean, and it facilitates laboratory studies on NO pathways.
 
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