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| Titel |
Evidence for vivianite formation and its contribution to long-term phosphorus retention in a recent lake sediment: a novel analytical approach |
| VerfasserIn |
M. Rothe, T. Frederichs, M. Eder, A. Kleeberg, M. Hupfer |
| Medientyp |
Artikel
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| Sprache |
Englisch
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| ISSN |
1726-4170
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| Digitales Dokument |
URL |
| Erschienen |
In: Biogeosciences ; 11, no. 18 ; Nr. 11, no. 18 (2014-09-26), S.5169-5180 |
| Datensatznummer |
250117610
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| Publikation (Nr.) |
 copernicus.org/bg-11-5169-2014.pdf |
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| Zusammenfassung |
| Vivianite, Fe3(PO4)2 · 8 H2O, is a ferrous iron
phosphate mineral which forms in waterlogged soils and
sediments. The phosphorus (P) bound in its crystal lattice is
considered to be immobilised because vivianite is stable under
anoxic, reducing, sedimentary conditions. Thus, vivianite formation
can make a major contribution to P retention during early
diagenesis. Much remains unknown about vivianite in sediments,
because technical challenges have rendered direct identification and
quantification difficult. To identify vivianite and assess its
significance for P burial during early diagenesis we studied the
consequences of a 1992/1993 in-lake application of FeCl3 and
Fe(OH)3 aimed at restoring Lake Groß-Glienicke (Berlin,
Germany). In a novel approach, we firstly applied a heavy-liquid
separation to the iron-rich surface sediments which allowed direct
identification of vivianite by X-ray diffraction in the high-density
(ρ > 2.3 g cm−3) sediment fraction. Secondly, we
assessed the contribution of vivianite to P retention, combining
results from chemical digestion with magnetic susceptibility data
derived from magnetic hysteresis measurements. Scanning electron
microscopy revealed that the dark blue spherical vivianite nodules
were 40–180 μm in diameter, and formed of platy- and
needle-shaped crystal aggregates. Although equilibrium calculations
indicated supersaturation of vivianite throughout the upper
30 cm of the sediment, the vivianite deposits were
homogeneously distributed within, and restricted to, the upper
23 cm only. Thus, supersaturated pore water alone cannot
serve as a reliable predictor for the in situ formation of
vivianite. In Lake Groß -Glienicke, vivianite formation continues
to be triggered by the artificial iron amendment more than
20 yr ago, significantly contributing to P retention in
surface sediments. |
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