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Titel Shoot-level monitoring of O3 and NOx fluxes of Scots pine (Pinus sylvestris L.)
VerfasserIn Johanna Joensuu, Nuria Altimir, Maarit Raivonen, Pasi Kolari, Petri Keronen, Timo Vesala, Jaana Bäck, Pertti Hari, Eero Nikinmaa
Konferenz EGU General Assembly 2011
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 13 (2011)
Datensatznummer 250053773
 
Zusammenfassung
O3 and nitrogen oxides (NOx=NO+NO2) are important atmospheric pollutants. Both are involved in atmospheric chemistry in various significant ways. O3 is a greenhouse gas. Both gases have potentially harmful effects on plants, but NOx can have nutritional as well as toxic effects. One of the processes underlying the atmospheric balance of O3 and NOx is their interaction with vegetation. Both are removed, absorbed, and NOrmx potentially also emitted by the foliage. The mechanisms driving these processes are not known in sufficient detail for accurate modeling of leaf-level O3 and NOx fluxes for the needs of i.e. global atmosphere-biosphere models. For example, the role of biogenic volatile compounds (BVOCs) in ozone scavenging and the role of nitrate in the biological and chemical NOx emissions require further research. The SMEAR II (Station of Measuring Forest Ecosystem-Atmosphere Relations) station in Hyytiälä, Finland, is well-known for its series of shoot-level O3 and NOx fluxes measured on Scots pine (Pinus sylvestris L.) in the field. Measurements from shoot-scale gas exchange chambers have provided valuable insights into O3 and NOx exchange (i.e. Raivonen & al. 2009, Altimir & al. 2006). The measuring system has since been upgraded with at least two major improvements: - A new chamber type was designed in order to remove the enclosure effect. The chamber is built as a sliding box that encloses the shoot only for the short time needed to make a measurement and otherwise allows the shoot to experience all occurring ambient conditions, including wind and rain. -In order to allow targeted flux measurement of NOx, not NOy, the molybdenum converter of the NOx analyser was replaced with a photolytic, NO2-specific one. We present preliminary results of O3 and NOx shoot-scale flux measurements after these improvements and discuss their value in increasing our understanding of the shoot-scale processes involving O3 ad NOx. Altimir N., Kolari P., Tuovinen J.-P., Vesala T., Bäck J., Suni T., Kulmala M. & Hari P. 2006. Foliage surface ozone deposition: a role for surface moisture? Biogeosciences 3 : 209-228. Raivonen M., Vesala T., Pirjola L., Altimir N., Keronen P., Kulmala M. & Hari P. 2009. Compensation point of NOx exchange: Net result of NOx consumption and production. Agric for Meteorol 149(6-7):1073-81.