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Titel Water-side turbulence enhancement of ozone deposition to the ocean
VerfasserIn C. W. Fairall, D. Helmig, L. Ganzeveld, J. Hare
Medientyp Artikel
Sprache Englisch
ISSN 1680-7316
Digitales Dokument URL
Erschienen In: Atmospheric Chemistry and Physics ; 7, no. 2 ; Nr. 7, no. 2 (2007-01-25), S.443-451
Datensatznummer 250004469
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/acp-7-443-2007.pdf
 
Zusammenfassung
A parameterization for the deposition velocity of an ocean-reactive atmospheric gas (such as ozone) is developed. The parameterization is based on integration of the turbulent-molecular transport equation (with a chemical source term) in the ocean. It extends previous work that only considered reactions within the oceanic molecular sublayer. The sensitivity of the ocean-side transport to reaction rate and wind forcing is examined. A more complicated case with a much more reactive thin surfactant layer is also considered. The full atmosphere-ocean deposition velocity is obtained by matching boundary conditions at the interface. For an assumed ocean reaction rate of 103 s−1, the enhancement for ozone deposition by oceanic turbulence is found to be up to a factor of three for meteorological data obtained in a recent cruise off the East Coast of the U.S.
 
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