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| Titel |
The peculiar case of Marosticano xenoliths: a cratonic mantle fragment affected by carbonatite metasomatism in the Veneto Volcanic Province (Northern Italy) |
| VerfasserIn |
Valentina Brombin, Costanza Bonadiman, Massimo Coltorti, M. Florencia Fahnestock, Julia G. Bryce, Andrea Marzoli |
| Konferenz |
EGU General Assembly 2017
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| Medientyp |
Artikel
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| Sprache |
en
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| Digitales Dokument |
PDF |
| Erschienen |
In: GRA - Volume 19 (2017) |
| Datensatznummer |
250142702
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| Publikation (Nr.) |
 EGU/EGU2017-6351.pdf |
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| Zusammenfassung |
| The Tertiary Magmatic Province of Veneto, known as Veneto Volcanic Province (VVP), in the Northern Italy, represents one of the most important volcanic provinces of the Adria Plate. It is composed by five volcanic districts: Val d’Adige, Marosticano, Mts. Lessini, Berici Hills and Euganean Hills. Most of the volcanic products are relatively undifferentiated lavas, from nephelinites to tholeiites in composition. Commonly VVP nephelinites and basanites carry mantle xenoliths. This study presents a petrological characterization of the new xenolith occurrence of Marosticano and comparison with previously studied VVP xenolith populations (i.e. from the Lessinean and Val d’Adige areas), which represent off-craton lithospheric mantle fragment affected by Na-alkaline silicate metasomatism (Siena & Coltorti 1989; Beccaluva et al., 2001; Gasperini et al., 2006).
Marosticano (MA) peridotites are anhydrous spinel-bearing lherzolites and harzburgites, which are geochemically well distinguishible from the other VVP mantle xenoliths. Primary minerals record the “most restitic” composition of the VVP sampled mantle, even calling the geochemical features of a sub-cratonic mantle. Olivines in both lherzolites and harzburgites show high Ni contents compared with the Fo values (Ni→ lherzolite: 2600-3620 ppm; harzburgite: 2600-3540 ppm; Fo → lh: 91-92; hz: 90-93) that follow the trend of olivine from a cratonic area (Kelemen, 1998). Orthopyroxenes have mg# values with 1:1 ratio with coexisting olivines and Al2O3 contents always <4 wt%, even for the most fertile lherzolite. Low Al2O3 (<5 wt%) associated with high Cr2O3 (>0.5 wt%) contents are also the chemical characteristics of the clinopyroxenes. On the whole both MA pyroxenes show major element contents that recall the characteristics of those from cratonic (sp-bearing) peridotites (e.g. from Greenland, South Africa and Tanzania; Downes et al., 2004). In addition, the relationship between the high Fo content of olivine and the high chromium contents (cr#=(Cr/(Cr+Al)X100); lh: 30-53; hz: 38-67) in coexisting spinel, out of the typical OSMA array (Arai, 1994b) is observed in typical on-craton mantle rocks (Downes et al., 2004).
To corroborate the cratonic “flavour” of these peridotites, in-situ trace element analyses show that Marosticano clinopyroxene have modified their residual characteristics by interaction with deep metasomatic melt, which was able to strong enrich in U, Th, LILE (Rb-Ba) and LREE with respect to the restitic preserved HREE and HFSE (e.g. Nb, Ta, Zr and Hf) contents. The general clinopyroxene trace element distribution and elemental ratios ((La/Yb)N and Ti/Eu; Coltorti et al., 1999) are consistent with enrichment provided by a carbonatitic rather than a silicate metasomatizing agent.
To characterize the chemical-physical frame of the MA mantle segment, peridotites equilibration temperatures and oxygen fugacities were also estimated and compared with those of the other VVP xenoliths. The latter comparison leads to i) Marosticano samples record relatively high oxidation conditions (as Mts. Lessini peridotites) in agreement with the range assigned to continental lithosphere (Foley et al., 2011) and ii) these T-fO2 values account for CO2 mole fractions dissolved in a potential metasomatic melt close to 1, further supporting the carbonatitic nature of the infiltrating melt.
In this case it can be speculated that the usually low oxidizing conditions of the cratonic mantle have been augmented by the interaction with a carbonatitic melt or with a CO2-rich fluid released by the reaction with a peridotitic matrix.
References
Arai, S., 1994b. Compositional variation of olivine chromian spinel in Mg-rich magmas as a guide to their residual spinel peridotites. Journal of Volcanology and Geothermal Research 59, 279-293.
Beccaluva L., Bianchini G., Bonadiman C., Coltorti M., Milani L., Salvini L., Siena F., Tassinari R. (2007). Intraplate lithospheric and sublithospheric components in the Adriatic domain: Nephelinite to tholeiite magma generation in the Paleogene Veneto Volcanic Province, Southern Alps. Geological Society of America, 131-152.
Beccaluva L., Bonadiman C., Coltorti M., Salvini L., Siena F. (2001). Depletion events, nature of metasomatizing agent and timing of enrichment processes in lithospheric mantle xenoliths from the Veneto Volcanic Province. Journal of Petrology, 42, 173-187.
Coltorti, M., Bonadiman, C., Hinton, R.W., Siena, F., Upton, B.G.J. (1999). Carbonatite metasomatism of the oceanic upper mantle: evidence from clinopyroxenes and glasses in ultramafic xenoliths of Grande Comore, Indian Ocean. Journal of Petrology, 40, 133-165.
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Foley, S.F. (2011). A reappraisal of redox melting in the Earth’s mantle as a function of tectonic setting and time. Journal of Petrology, 52, 1363-1391.
Gasperini D., Bosch D., Braga R., Bondi M., Macera P., Morten L. (2006). Ultramafic xenoliths from the Veneto Volcanic Province (Italy): Petrological and geochemical evidence for multiple metasomatism of the SE Alps mantle lithospere. Geochemical Journal, 40, 377-404.
Kelemen, P.B., Hart, S.R., Bernstein, S. (1998). Silica enrichment in the continental upper mantle via melt/rock reaction. Earth and Planetary Science Letters, 164, 387-406.
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Siena F., Coltorti M. (1989). Lithospheric mantle evolution: evidences from ultramafic xenoliths in the Lessinean volcanics (Northern Itlay). Chemical Geology, 77, 347-364. |
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