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Titel Using oxygen isotopes to quantitatively assess residual CO2 saturation during the CO2CRC Otway Stage 2B Extension residual saturation test
VerfasserIn Sascha Serno, Gareth Johnson, Tara C. LaForce, Jonathan Ennis-King, Ralf Haese, Chris Boreham, Lincoln Paterson, Barry M. Freifeld, Paul J. Cook, Dirk Kirste, R. Stuart Haszeldine, Stuart M. V. Gilfillan
Konferenz EGU General Assembly 2016
Medientyp Artikel
Sprache en
Digitales Dokument PDF
Erschienen In: GRA - Volume 18 (2016)
Datensatznummer 250122367
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2016-1388.pdf
 
Zusammenfassung
Recent research has shown that the oxygen isotope ratio (δ18O) of reservoir water can change due to isotopic equilibrium exchange with injected CO2. These changes have been successfully used to assess reservoir saturation with CO2. We present the first δ18O measurements from a single-well experiment, the CO2CRC Otway 2B Extension project, used to estimate levels of residual trapping of CO2. Following the initiation of the drive to residual saturation in the reservoir, reservoir water δ18O decreased, as predicted from the baseline isotope ratios of water and CO2, over a time span of only a few days. The isotope shift in the near-wellbore reservoir water is the result of isotope equilibrium exchange between residual CO2 and water. For the region further away from the well, the isotopic shift in the reservoir water can also be explained by isotopic exchange with mobile CO2 from ahead of the region driven to residual, or continuous isotopic exchange between water and residual CO2 during its back-production, complicating the interpretation of the change in reservoir water δ18O in terms of residual saturation. A small isotopic distinction of the baseline water and CO2 δ18O, together with issues encountered during the field experiment procedure, further prevents the estimation of residual CO2 saturation levels from oxygen isotope changes without significant uncertainty. The consistency of oxygen isotope-based near-wellbore saturation levels and independent estimates based on pulsed neutron logging indicates the potential of using oxygen isotope as an effective inherent tracer for determining residual saturation on a field scale within a few days.