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Titel An improved inlet for precisely measuring the atmospheric Ar/N2 ratio
VerfasserIn T. W. Blaine, R. F. Keeling, W. J. Paplawsky
Medientyp Artikel
Sprache Englisch
ISSN 1680-7316
Digitales Dokument URL
Erschienen In: Atmospheric Chemistry and Physics ; 6, no. 5 ; Nr. 6, no. 5 (2006-04-18), S.1181-1184
Datensatznummer 250003722
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/acp-6-1181-2006.pdf
 
Zusammenfassung
The atmospheric Ar/N2 ratio is expected to be useful as a tracer of air-sea heat exchange, but this application has been hindered in part due to sampling artifacts. Here we show that the variability in δ(Ar/N2) due to thermal fractionation at the inlet can be on the order of 40-80 per meg, and we introduce the use of an aspirated solar shield that successfully minimizes such fractionation. The data collected using this new inlet have a mean diurnal cycle of 1.0 per meg or less, suggesting that any residual thermal fractionation effect is reduced to this level.
 
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