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Titel Isotopic (18O) signature of CO2-H2O vapor exchange in the vadose air of Nerja cave (Malaga, Spain)
VerfasserIn Iñaki Vadillo, Lucía Ojeda, José Benavente, Cristina Liñán, Yolanda del Rosal, Francisco Carrasco
Konferenz EGU General Assembly 2017
Medientyp Artikel
Sprache en
Digitales Dokument PDF
Erschienen In: GRA - Volume 19 (2017)
Datensatznummer 250149934
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2017-14342.pdf
 
Zusammenfassung
In caves, carbon dioxide contents and its δ13C signature have been widely studied to provide information about the ventilation regime and the source of carbon dioxide. However, less has been researched about δ18O signature in vadose air. We analysed cave-air samples for the CO2 concentration and oxygen isotopic composition from a monthly sampling campaigns for two years within different halls in Nerja cave. In general terms, ventilation controls the variation of CO2 content seasonally, showing two distinct modes with the highest values in summer. The δ18O values range from -8.74 to +0.47 ‰ being maximum in January and minimum in September, coinciding with the lowest and highest humidity values within the cave respectively. We found that a gas exchange between δ18O-CO2 and δ18O-H2O vapor is carried out and pattern is repeated every season, showing the importance that water has in karst environment.