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Titel Inorganic carbon and fossil organic carbon are source of bias for quantification of sequestered carbon in mine spoil
VerfasserIn Olga Vindušková, Jan Frouz
Konferenz EGU General Assembly 2016
Medientyp Artikel
Sprache en
Digitales Dokument PDF
Erschienen In: GRA - Volume 18 (2016)
Datensatznummer 250129020
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2016-9080.pdf
 
Zusammenfassung
Carbon sequestration in mine soils has been studied as a possibility to mitigate the rising atmospheric CO2 levels and to improve mine soil quality (Vindušková and Frouz, 2013). Moreover, these soils offer an unique opportunity to study soil carbon dynamics using the chronosequence approach (using a set of sites of different age on similar parent material). However, quantification of sequestered carbon in mine soils is often complicated by fossil organic carbon (e.g., from coal or kerogen) or inorganic carbon present in the spoil. We present a methodology for quantification of both of these common constituents of mine soils. Our recommendations are based on experiments done on post-mining soils in Sokolov basin, Czech Republic. Here, fossil organic carbon is present mainly as kerogen Type I and II and represents 2-6 wt.% C in these soils. Inorganic carbon in these soils is present mainly as siderite (FeCO3), calcite (CaCO3), and dolomite (CaMg(CO3)2). All of these carbonates are often found in the overburden of coal seams thus being a common constituent of post-mining soils in the world. Vindušková O, Frouz J, 2013. Soil carbon accumulation after open-cast coal and oil shale mining in Northern Hemisphere: a quantitative review. ENVIRONMENTAL EARTH SCIENCES, 69: 1685-1698. Vindušková O, Dvořáček V, Prohasková A, Frouz J. 2014. Distinguishing recent and fossil organic matter — A critical step in evaluation of post-mining soil development – using near infrared spectroscopy. ECOLOGICAL ENGINEERING. 73: 643-648. Vindušková O, Sebag D, Cailleau G, Brus J, Frouz J. 2015. Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen. ORGANIC GEOCHEMISTRY, 89-90:14-22.