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Titel Investigation of the Nitrogen Dioxide Pollution in Urban Areas using a New Portable ICAD Instrument
VerfasserIn Martin Horbanski, Denis Pöhler, Tim Adler, Johannes Lampel, Florian Kanatschnig, Tobias Oesterle, Miriam Reh, Ulrich Platt
Konferenz EGU General Assembly 2016
Medientyp Artikel
Sprache en
Digitales Dokument PDF
Erschienen In: GRA - Volume 18 (2016)
Datensatznummer 250127774
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2016-7684.pdf
 
Zusammenfassung
Nitrogen oxides (NOx) and especially nitrogen dioxide (NO2), are still among of the most problematic pollutants in urban areas not only in developing, but also in industrialized countries. Despite the measures taken to reduce their emissions, NO2 concentrations in many urban areas exceed the WHO recommended limits of 40 μg∕m3 for annual mean and 200 μg∕m3 for 1 hour mean. Additionally it is known that the NO2 concentration in urban areas has a strong spatial and temporal variability, due to the large number of NOx emitting point sources (mainly traffic) found in densely populated areas. However, the layout of air monitoring networks in most urban areas, installed to continuously monitor the officially prescribed NO2 limits, does not reflect the high spatial variability because they only conduct measurements at a single or few selected sampling points, mainly on major roads, which are often not representative for the whole urban area. At present these uncertainties about the spatial NO2 distribution constitute severe limitations for the assessment of health risks, for the quality of chemical model calculations, and for developing effective measures to reduce NOx emissions. We developed a new light-weight and portable ICAD (Iterative Cavity Enhanced DOAS) instrument which detects NO2 at a detection limit as low as 0.2 μg∕m3 with a high time resolution of seconds. The instrument is based on the Cavity Enhanced (CE-) DOAS technique, which directly identifies and quantifies NO2 by its differential optical absorption. Therefore, it does not suffer from interferences by other trace gas species like O3 or NOy. This is a great advantage over other NO2 instruments (e.g. solid state detectors or chemiluminescence instruments). We present the result of ICAD NO2 measurements, which we recently performed in more than 10 German cities. The ICAD instrument was mounted on mobile platforms like cars and bicycles, measuring the NO2 concentrations along carefully selected tracks. Also several stationary measurements were performed at selected sites. We found that high NO2 concentrations exceeded pollution limits across extensive areas of the cities. Contrary to expectations we found high NO2 concentrations also away from heavily traveled roads e.g. in residential areas and close to kindergardens and schools and even indoors. Thus, the exposure of the populations to NO2 is much higher than expected, which results in higher health risks, particularly for children and elderly people who are risk groups.