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Titel Carbon Dioxide Ice Structure and Density in the Martian Mesosphere
VerfasserIn Thomas Mangan, Benjamin Murray
Konferenz EGU General Assembly 2016
Medientyp Artikel
Sprache en
Digitales Dokument PDF
Erschienen In: GRA - Volume 18 (2016)
Datensatznummer 250123364
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2016-2599.pdf
 
Zusammenfassung
CO2 ice has been grown experimentally via deposition in order to mimic ice formation in Martian mesospheric CO2 clouds. This is achieved through the use of a low temperature and low pressure controlled stage mounted within an X-ray diffractomer (XRD). XRD patterns of CO2 deposited at temperatures of 80 – 130 K and pressures below 1 mbar were analysed using a Rietveld refinement method and fitted to a crystalline cubic structure (space group Pa3). This crystal structure is consistent with XRD patterns also taken of dry ice. CO2 ice densities were then determined from the refined lattice parameters across the 80 – 130 K range and extrapolated using literature values resulting in a temperature dependent density parameter valid over 80 – 195 K. This temperature dependent parameter for CO2 ice density was applied to nucleation, sedimentation and growth rates of CO2 ice particles under conditions relevant to the Martian mesosphere. The results were then compared to commonly used literature values, illustrating the need for the use of temperature dependent CO2 ice densities.