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Titel 87Sr/86Sr as a quantitative geochemical proxy for 14C reservoir age in dynamic, brackish waters: assessing applicability and quantifying uncertainties.
VerfasserIn Bryan Lougheed, Jeroen van der Lubbe, Gareth Davies
Konferenz EGU General Assembly 2016
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 18 (2016)
Datensatznummer 250122080
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2016-1017.pdf
 
Zusammenfassung
Accurate geochronologies are crucial for reconstructing the sensitivity of brackish and estuarine environments to rapidly changing past external impacts. A common geochronological method used for such studies is radiocarbon (14C) dating, but its application in brackish environments is severely limited by an inability to quantify spatiotemporal variations in 14C reservoir age, or R(t), due to dynamic interplay between river runoff and marine water. Additionally, old carbon effects and species-specific behavioural processes also influence 14C ages. Using the world’s largest brackish water body (the estuarine Baltic Sea) as a test-bed, combined with a comprehensive approach that objectively excludes both old carbon and species-specific effects, we demonstrate that it is possible to use 87Sr/86Sr ratios to quantify R(t) in ubiquitous mollusc shell material, leading to almost one order of magnitude increase in Baltic Sea 14C geochronological precision over the current state-of-the-art. We propose that this novel proxy method can be developed for other brackish water bodies worldwide, thereby improving geochronological control in these climate sensitive, near-coastal environments.