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Titel Hydrogen chloride 37Cl/35Cl isotopic ratio field analyzer for the investigation of volcanic plumes
VerfasserIn Francesco D'amato, Mike Burton, Antonio Chiarugi, Silvia Viciani
Konferenz EGU General Assembly 2015
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 17 (2015)
Datensatznummer 250113290
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2015-13488.pdf
 
Zusammenfassung
We present a new analyzer for the in-field measurement of the isotopic ratio 37Cl/35Cl in the hydrogen chloride emitted by volcanoes, developed within the frame of the ERC Project CO2Volc (Grant 279802). The Project aims to the measurement of several molecular species in the volcanic plumes. The analyzer is based on molecular spectroscopy. The volcanic plume interacts in a multipass cell with two laser beams at suitable wavelengths. From the absorptions of the two beams by the two isotopologues the isotopic ratio is retrieved. We report here the results of the laboratory checks of the instrument, and the results of a measurement campaign carried out on Etna and Vulcano. The campaign aimed to verify not only the in-field performances of the analyzer but also to assess its robustness in such a hostile environment.