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Titel Clumped isotope constraints on fluid processes and heat advection during late Variscan brittle failure of carbonate rocks
VerfasserIn Paul Dennis, Daniel Myhill, Neil Allanach, Alexandra Forman, Alina Marca
Konferenz EGU General Assembly 2015
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 17 (2015)
Datensatznummer 250111277
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2015-11379.pdf
 
Zusammenfassung
Clumped isotope temperatures (T(δ47)) for macroscopic hydrothermal calcite veins from the Lower Carboniferous limestone of the Peak District, U.K. and the Clare Basin, Ireland indicate that late Variscan brittle failure is accompanied by high rates of fluid flow and heat advection along fault surfaces. Moreover, the veins are often zoned with regard to both temperature and oxygen isotope composition indicating that fluid movement is episodic and occurs in pulses. A striking feature of the data sets for both the Peak District and Clare Basin is that veins, including multiple samples from single veins, plot on well defined two end-member mixing lines in T-δ18Ofluid space. The data for veins in the Clare Basin indicate that they precipitated at a temperature between 100°and 160˚ C, and for the Peak District between 30°and 100˚ C. The veins precipitate from a mixed fluid comprised of: (i) a hot, isotopically evolved end member (T>160˚ C, δ18Ofluid > +12V SMOW) and; (ii) a cooler, isotopically depleted fluid more characteristic of meteoric groundwaters (T