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Titel The Werkendam natural CO2 accumulation: An analogue for CO2 storage in depleted oil reservoirs
VerfasserIn Pieter Bertier, Andreas Busch, Suzanne Hangx, Niko Kampman, Georg Nover, Helge Stanjek, Philipp Weniger
Konferenz EGU General Assembly 2015
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 17 (2015)
Datensatznummer 250107958
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2015-7683.pdf
 
Zusammenfassung
The Werkendam natural CO2 accumulation is hosted in the Röt (Early Triassic) sandstone of the West Netherlands Basin, at a depth of 2.8 km, about 20 km south-east of Rotterdam (NL). This reservoir, in a fault-bound structure, was oil-filled prior to charging with magmatic CO2 in the early Cretaceous. It therefore offers a unique opportunity to study long-term CO2-water-rock interactions in the presence of oil. This contribution will present the results of a detailed mineralogical and geochemical characterisation of core sections from the Werkendam CO2 reservoir and an adjacent, stratigraphically equivalent aquifer. X-ray diffraction combined with X-ray fluorescence spectrometry revealed that the reservoir samples contain substantially more feldspar and more barite and siderite than those from the aquifer, while the latter have higher hematite contents. These differences are attributed to the effects hydrocarbons and related fluids on diagenesis in the closed system of the CO2 reservoir versus the open-system of the aquifer. Petrophysical analyses yielded overall higher and more anisotropic permeability for the reservoir samples, while the porosity is overall not significantly different from that of their aquifer equivalents. The differences are most pronounced in coarse-grained sandstones. These have low anhydrite contents and contain traces of calcite, while all other analyzed samples contain abundant anhydrite, dolomite/ankerite and siderite, but no calcite. Detailed petrography revealed mm-sized zones of excessive primary porosity. These are attributed to CO2-induced dissolution of precompactional, grain-replacive anhydrite cement. Diagenetic dolomite/ankerite crystals are covered by anhedral, epitaxial ankerite, separated from the crystals by bitumen coats. Since these carbonates were oil-wet before CO2-charging, the overgrowths are interpreted to have grown after CO2-charging. Their anhedral habit suggests growth in a 2-phase water-CO2 system. Isotopic analysis yielded an internal source for all carbon, oxygen and sulphur, which implies that mineral trapping of CO2 was insignificant.