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Titel New data about the reasons of periodic sulfide crystallization-dissipation in ultrabasic magmas.
VerfasserIn Alex Asavin, Alex Ariskin
Konferenz EGU General Assembly 2015
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 17 (2015)
Datensatznummer 250103368
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2015-2779.pdf
 
Zusammenfassung
Possible manifestation of sulfide mineralization in the intrusive complexes of basic and ultrabasic rocks depends on the two main factors: sulphide liquid immisiblity and segregation (concentration) of sulfide minerals as crystallization primary and derived magmas. One of the news models in order to calculate the saturation concentration of sulfur basic and ultrabasic melts proposed in the (program SULSAT [Ariskin et.al., 2013]). In this model, the first time takes into account the effect of nickel on the solubility and the composition of the sulfide phase with variable composition (FeS-NiS). Thanks to the detailed evaluation of our conditions of crystallization of olivine and spinel meimechite and picritic melts [Asavin 2014]. an opportunity to assess the value SCSS (Sulfur Content at Sulfide Saturation) from model SULSAT mantle melts in the ultrabasic magma camera. We obtained, the large statistical material on the distribution of sulfur in the samples groundmass and in the bulk rocks, we can reliably assess the level of actual sulfur content in natural melts (Tabl1-2). According theoretical model we calculated SCSS in natural volcanic melts - meimechites and picrites (lava and dyke Maimecha-Kotuy province Siberia [Asavin 2014]). Tabl.1 Calculation for meimechite samples. Sample.T(C)-Log fO2#S (wt%)S6+/#SSiO2 MgO CaO Na2OK2ONiOS (ppm) 251_2 15144.59 0.43 0.40 41.9625 9.23 0.16 0.7 0.14237 251_2 15104.62 0.48 0.42 39.9322.937.13 0.24 0.87 0.12270 50C 13406.09 0.31 0.29 40.7615.0114.630.35 0.4 0.32 8313 14754.9 0.32 0.28 42.5621.7811.4 0.3 0.23 0.10139 85_19 14664.97 0.40 0.39 42.0421.069.65 0.44 1.31 0.07139 85_22 14814.85 0.40 0.41 41.4422.1310.140.44 1.28 0.10539 85_27 14984.72 0.73 0.51 41.1 23.332.56 0.76 1.01 0.241120 85_38 15804.09 0.51 0.41 38.1727.096.1 0.1 0.2 0.15197 85_38 15884.03 0.50 0.41 41.0729.936.74 0.1 0.22 0.15291 195 14714.93 0.37 0.30 39.2 19.7 7.38 0.4 0.59 0.17661 195 15254.5 0.41 0.34 41.4225 9.04 0.47 0.4 0.20700 199 15694.17 0.48 0.43 40.3626.335.22 0.19 1 0.19491 201 15174.57 0.45 0.40 39.0523.278.59 0.16 0.83 0.00194 202 15204.54 0.33 0.39 38.8423.6210.860.26 0.76 0.09192 202 14954.74 0.44 0.55 40.9221.329.44 0.71 4.75 0.09177 204 14475.13 0.46 0.46 41.1620.448.99 1.05 1.08 0.17316 204 15884.03 0.48 0.46 39.5227.555.69 0.5 0.74 0.19500 207 16273.76 0.40 0.45 40.7430.714.85 0.57 0.27 0.19998 209 16803.4 0.48 0.49 37.8 32.684.64 0.91 0.08 0.23340 215 15444.36 0.38 0.41 39.3824.788.38 0.31 0.78 0.20891 215 16033.93 0.44 0.42 40.1830.127.65 0.22 0.5 0.20897 87_216 14575.05 0.53 0.52 39.4819.978 1.46 1.86 0.21300