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Titel Coupling 2H and 18O biomarker results provides new insight into palaeohumidity changes in East Africa during the last glacial
VerfasserIn Johannes Hepp, Roland Zech, Mario Tuthorn, Bruno Glaser, Kazimierz Różański, Wolfgang Zech, Michael Zech
Konferenz EGU General Assembly 2015
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 17 (2015)
Datensatznummer 250101753
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2015-952.pdf
 
Zusammenfassung
We couple compound-specific δ2H results of leaf wax-derived n-alkanes with compound-specific δ18O results of hemicellulose-derived sugars extracted from the loess-paleosol-sequence Maundi (3˚ 10’27.5”S, 37˚ 31’05.8”E) located on the south-eastern slopes of Mt. Kilimanjaro at ~ 2780 m above sea level. This coupled biomarker approach allows inter alia establishing a ca. 100 ka record of the isotopic composition of leaf water. Accordingly, the deuterium-excess of leaf water may serve as a proxy for palaeohumidity. Furthermore, the coupled biomarker approach allows reconstructing the isotopic composition of palaeoprecipitation (by using the slope the local evaporation line derived from a simple Craig-Gordon model). Our results suggest that sedimentary δ2Hleaf-wax records should not be interpreted directly in terms of reflecting δ2Hprec because variable leaf water evaporative enrichment can strongly overprint the δ2Hprec signal. The Maundi δ2Hn-alkane record can be compared with δ2Hwax records from Lake Challa, Lake Tanganyika and Lake Malawi. Accordingly, the Maundi δ2Hn-alkane record is generally in good agreement with the Lake Challa and the Lake Tanganyika δ2Hwax records. However, a clear altitude effect can be seen in the δ2H records (Maundi: 2780 m a.s.l.; Lake Challa: 880 m a.s.l.; Lake Tanganyika: 773 m a.s.l.; Lake Malawi: 474 m a.s.l.). Moreover, the Maundi δ2Hn-alkane record reveals a clear smaller range compared to the other δ2Hwax records. Finally, especially the Lake Malawi δ2Hwax record reveals also clearly different features than the other available δ2Hwax records. These differences resulted in different interpretations of the δ2Hwax records (amount effect vs. source effect). Our coupled δ18Osugar and δ2Hn-alkane approach sheds new light into this discussion. In brief, reconstructed low deuterium-excessleaf-water values during the African Humid Period (AHP) indicate humid climatic conditions. By contrast, higher deuterium-excessleaf-water values indicate that arid climatic conditions prevailed during the Younger Dryas (YD), the Last Glacial Maximum (LGM) and during a mega drought period (MD) having occurred ~ 70-60 ka BP. Including the Maundi precipitation record in a circum pacific comparison may help to identify the drivers of past isotopic composition on east equatorial African precipitation.