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Titel Synthetic enstatite for the comparison with ground-based and VIRTIS-M/ROSETTA reflectance spectra of asteroid 2867 Šteins in the VIS and IR
VerfasserIn Kathrin Markus, Gabriele Arnold, Harald Hiesinger, Arno Rohrbach, Fabrizio Capaccioni, Gianrico Filacchione, Federico Tosi, Maria Cristina De Sanctis, Maria Teresa Capria, Eleonora Ammannito, Stephane Erard
Konferenz EGU General Assembly 2014
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 16 (2014)
Datensatznummer 250097730
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2014-13341.pdf
 
Zusammenfassung
Asteroid 2867 Šteins was observed by the Rosetta spacecraft on September 5, 2008. During this close encounter, the VIRTIS spectrometer (Visible and Infrared Thermal Imaging Spectrometer) aboard Rosetta acquired spectra of Šteins in the wavelength range from 0.2μm to 5μm [1]. We compare ground-based VIS and NIR reflectance spectra of Šteins [2-7] with reflectance spectra obtained by OSIRIS (Optical, Spectrocopic and Infrared Remote Imaging System) [8] and VIRTIS-M during the fly-by and with laboratory reflectance spectra of enstatite chondrites (aubrites) and minerals (enstatite, oldhamite, albite). Ground-based and fly-by observations show an overall flat spectrum with the typical E[II]-type absorptions bands at 0.49μm and ~0.9μm. E-type asteroids have been associated to aubrites due to their high reflectance and overall featureless spectrum. The lack of absorption bands at 1μm and 2μm indicates that Šteins’ surface has no Fe-bearing pyroxenes or olivines. It is well known that even small amount of Fe in enstatite lead to prominent absorption features in the IR at 1μm and 2μm. Terrestrial samples of enstatite usually contain several mol% of FeO and therefore exhibit the absorption features. Pure enstatite is extremely rare. A sample of enstatite with 2.5mol% of FeO already shows distinct absorptions features at 1μm and 2μm [9]. To have available sufficient amounts of pure enstatite for our spectral studies, we developed a technique for synthesis of enstatite. Enstatite has 3 stable polymorphs with clinoenstatite, orthoenstatite, and protoenstatite being stable at low (600°C), and high (>1000°C) temperatures [10]. Orthoenstatite and protoenstatite are orthorhombic, while clinoenstatite is monoclinic. Orthoenstatite is abundant in terrestrial rocks and in meteorites. Clinoenstatite is known from meteorites [10, 11]. Shear deformation and quenching of orthoenstatite or protoenstatite induces inversion to clinoenstatite [10]. Clinoenstatite in enstatite chondrites and aubrites formed presumably by crystallization from a melt and subsequent quenching and mechanical deformation (brecciation) [11]. We synthesized powders of orthoenstatite and clinoenstatite. Following the synthesis we used XRPD to discriminate between the polymorphs. The grain sizes of the samples were determined using SEM pictures of the samples and are comparable to the