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Titel Thermodynamic forecast for dry C-O-S fluid and possible link with 2012-2013 Tolbachik eruption.
VerfasserIn Alexander Simakin, Vera Deviatova, Michael Zelensky
Konferenz EGU General Assembly 2014
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 16 (2014)
Datensatznummer 250092406
Publikation (Nr.) Volltext-Dokument vorhandenEGU/EGU2014-6748.pdf
 
Zusammenfassung
Carbon and sulfur transfer in the upper mantle and lower crust can be coupled due to the stability of their mutual compounds COS and CS2. These components are registered in the volcanic gases in the rather minor quantities [Symonds et al., 1994] due to the effects of decompression, oxidation and hydration. At the same time in the dry reduced conditions at the elevated pressures these components along with CO may comprise more than half of carbon bearing fluid as shown by thermodynamic calculations [Simakin, 2014]. Carbon monoxide and COS were suggested as potential carriers for Ni and PGE in reduced carbonic fluids at magmatic PT conditions. Moreover at the unrealistically reduced for the Earth oxygen fugacities fO2