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Titel Tracing fluid-induced metasomatism across a blueschist-facies shear zone (Sesia-Lanzo zone, Western Alps) using boron isotopes
VerfasserIn Ralf Halama, Matthias Konrad-Schmolke, Horst Marschall, Michael Wiedenbeck
Konferenz EGU General Assembly 2013
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 15 (2013)
Datensatznummer 250082198
 
Zusammenfassung
Boron (B) is a useful tracer for slab-mantle-arc fluid transport and recycling processes in subduction zones due to its high mobility in hydrous fluids and its significant isotope fractionation by fluid-rock interaction. Although B isotope geochemistry provides key evidence for slab to arc transfer by aqueous fluids, B isotope data on natural high-pressure metamorphic rocks are still scarce and the effects and extent of fluid-rock interaction remain poorly studied. Secondary ion mass spectrometry (SIMS) analyses generally confirm that slab dehydration significantly lowers δ11B of subducted oceanic crust and sediments, but the lack of a systematic relationship with peak metamorphic conditions suggests additional processes have affected the exhumed rocks. Here, we evaluate the effects of deformation and fluid flux on the B isotopic composition of phengitic mica along a structural profile with strain- and recrystallization gradient across a major crustal shear zone that separates two tectonometamorphic units in the Sesia-Lanzo Zone (SLZ), Western Alps. Weakly deformed, eclogite-facies samples contain phengites that show significant major element compositional differences between pristine cores and overprinted rims. Samples from the blueschist-facies shear zone contain fine-grained, mylonitic phengite with a major element composition similar to the rims. Lithium (Li) and B concentrations show a slight decrease in the overprinted rims (38-50 ppm Li, 30-33 ppm B) compared to the cores (55-69 ppm Li, 44-48 ppm B), and a significant drop to