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Titel Trace gas - ice interaction measurements with microstructure control
VerfasserIn Erik S. Thomson, Thorsten Bartels-Rausch, Fabienne Riche, Martin Schneebeli, Markus Ammann
Konferenz EGU General Assembly 2013
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 15 (2013)
Datensatznummer 250078602
 
Zusammenfassung
The surfaces of snow and ice have significant impact on the physicochemistry and thus chemical budgets of near-surface air. In these environments the availability of chemical species depends sensitively on the structural character of the snowpack and its transport parameters. As a result the thermodynamic and kinetic characteristics of trace gas – ice interactions are of fundamental interest and have potential implications in geochemical cycling and climate. We have developed a unique experimental method for measuring trace gas – ice interactions with careful control of ice microstructure. More specifically, the grain size at the ice-air interface can be varied and analyzed. The new Ice Flow Tubes allow us to sensitively explore the temperature dependence of trace gas – ice interactions with a high resolution and minimal foreign body surfaces. In preliminary experiments H2O2 has been used to successfully demonstrate the working principle, and results are indicative of the power and utility of the new method.