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Titel Bromine monoxide evolution in early plumes of Mutnovsky and Gorely (Kamchatka, Russia)
VerfasserIn N. Bobrowski, L. Vogel, U. Platt, S. Arellano, B. Galle, T. Hansteen, S. Bredemeyer
Konferenz EGU General Assembly 2012
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 14 (2012)
Datensatznummer 250064422
 
Zusammenfassung
In September 2011 during the 11th Field Workshop of the Commission on the Chemistry of Volcanic gases (CCVG) Multi-axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements and Mini-DOAS traverses were carried out at the volcanoes Mutnovsky and Gorely in Kamchatka, Russia. A SO2 camera was applied in parallel. Mutnovsky (52˚ 27’N, 158˚ 12’E, 2322 m.a.s.l.) is a stratovolcano whose volcanic activity is currently characterized mainly by strong fumarolic degassing. Gorely (52˚ 33N, 158˚ ’02E, 1829 m) is a caldera volcano which currently comprises an acidic crater lake a large, and often displays a non-condensing volcanic plume. It is a peculiarity that the plume of Gorely volcano cannot (or only rarely) be recognized by visual observation, even though it has a similar emission source strength as Etna (several thousand tons of gas every day). BrO/SO2 ratios were for the first time determined in the young volcanic plumes of both Mutnovsky and Gorely volcanoes on the 5th and 6thSeptember 2011, respectively. The instruments were set up at a distance to the summit of about 8 km in the case of Mutnovsky and 4 km in the case of Gorely. Measurements were carried out at various azimuth angles and therefore several plume ages. The investigated plume age could be calculated from the wind velocity determined by the SO2 camera which was applied simultaneously with the MAX DOAS system. Furthermore, plume traverses at Mutnovsky and Gorely yielded SO2 emission fluxes of about 500 t/d and 1000 t/d, respectively. The BrO/SO2 ratios range from below 0.5 x 105 up to about 6 x 105 with increasing plume ages and follow therefore the previously observed trend at other volcanic sites. The data will be compared with earlier studies, e.g., at Mt Etna. Possible influence of the different surrounding conditions, in particular the condensation, is discussed.