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Titel HOx Budgets during HOx Comp: a Case Study of HOx Chemistry under NOx limited Conditions
VerfasserIn Yasin Elshorbany, Jörg Kleffmann, Ralf Kurtenbach, Peter Wiesen, Andreas Hofzumahaus, Hans-Peter Dorn, Eric Schlosser, Yugo Kanaya, Ayako Yoshino, Satoshi Nishida, Yoshizumi Kajii
Konferenz EGU General Assembly 2011
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 13 (2011)
Datensatznummer 250057746
 
Zusammenfassung
Recent studies have shown that measured OH radical concentrations under low NOx, rural conditions are many times higher than modelled OH, from which NO independent OH regeneration pathways were proposed. In this study, a detailed analysis of the HOx radical budgets under low NOx, rural conditions were investigated employing a zero dimensional photochemical box model based on the Master Chemical Mechanism (MCMv3.1). The model results were compared and contrasted with highly reliable HOx radical measurements performed during the international HOxComp campaign carried out in Jülich, Germany during summer, 2005. Two different air masses were experienced by the measurement site denoted as high NOx (1-3 ppbv) and low NOx (