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Titel Line-mixing effects on spectral shape and consequences for laboratory and atmospheric spectra analyses
VerfasserIn Ha Tran, Jean-Michel Hartmann, Geoffrey Toon
Konferenz EGU General Assembly 2011
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 13 (2011)
Datensatznummer 250054986
 
Zusammenfassung
Collisional line-mixing is a process which is known to affect the treatment of atmospheric spectra for several species. Recent works on the modelling of line-mixing effects will be presented for CO2, CH4 and O3. It will be shown that the widely used Voigt profile leads to large discrepancies with respect to measured spectra and accounting for line-mixing effects is unavoidable to correctly model measurements. Comparisons between laboratory, atmospheric spectra and simulations using our models show good agreements. However, small but systematic errors on the residuals still remain indicating that more refined works on spectral shape are needed.