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Titel Experimental constraints on the origin of aphyric phonolitic magmas
VerfasserIn Matteo Masotta, Carmela Freda, Mario Gaeta
Konferenz EGU General Assembly 2011
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 13 (2011)
Datensatznummer 250051909
 
Zusammenfassung
Large explosive phonolitic eruptions are commonly characterized by aphyric juvenile eruptive products. Processes leading to the origin of such large volumes of crystal-poor differentiated magmas are still uncertain. A large number of processes, indeed, may be invoked to explain crystal-melt separation (i.e. crystal settling, compaction, filter-press), but the efficacy of each process in generating significant volumes of aphyric eruptible magmas is questionable. Seeking for an answer, we have experimentally investigated crystallization in presence of a thermal gradient as a possible mechanism for the origin of large volume of differentiated aphyric melts. Our case study is the phonolitic volcanism of Sabatini Volcanic District (SVD), Central Italy. We used a natural tephri-phonolitic composition as starting material and performed thermal gradient-driven crystallization experiments in order to simulate the crystallization process in a thermally zoned magma chamber. In the experimental products, crystallization degree and melt composition vary as a function of the thermal gradient. In particular, melt composition ranges from tephri-phonolitic (starting material) at the bottom of the charge (hottest and aphyric zone) to phonolitic at the top (cooler and heterogeneously-crystallized zone), reproducing the liquid line of descent observed in equilibrium experiments. Backscattered images of experimental products clearly evidence: i) the aphyric tephri-phonolitic melt region at the bottom of the charge; ii) a drop-shaped crystal clustering in the middle zone; and iii) large aphyric belts and pockets (up to 100 µm wide) of phonolitic melt, with large deformed-shaped sanidine occurring at their margin, at the charge top region. Intriguingly, these batches of aphyric phonolitic melt are separated from the highly crystallized zone by a thick mush of crystals (clinopyroxene+plagioclase). According to our experimental data a mere crystal settling process cannot explain the upward accumulation of the aphyric phonolitic melt whereas the high viscosity of the crystalline region would limit the efficacy of compaction and filter-press mechanisms. Alternatively, the brittle behavior of the crystal framework (glass<10% vol.) could have lead to the instability of the crystal mush and to the abrupt extrusion of the interstitial glass forming the phonolitic belts and pockets. The occurrence of a fast and intense segregation of the interstitial melt is supported by abundance of deformed crystals of sanidine. Textural features and phase relations observed in the experimentally-reproduced crystal mush are in good agreement with observations from crystalline ejecta emplaced in large phonolitic eruptions of SVD, representative of the crystallizing boundary layer of a phonolitic magma chamber.