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| Titel |
Evidence for long term deep CO2 confinement below thick Jurassic shales at Montmiral site (SE Basin of France) |
| VerfasserIn |
Y. Rubert, C. Ramboz, Y. M. Le Nindre, C. Lerouge, M. Lescanne |
| Konferenz |
EGU General Assembly 2009
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| Medientyp |
Artikel
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| Sprache |
Englisch
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| Digitales Dokument |
PDF |
| Erschienen |
In: GRA - Volume 11 (2009) |
| Datensatznummer |
250029573
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| Zusammenfassung |
| Studies of natural CO2 analogues bring key information on the factors governing the long term (>1My) stability/instability of future anthropogenic CO2 storages. The main objective of this work is to trace the deep-origin CO2 migrations in fractures in the Montmiral CO2 deep natural occurrence (Valence Basin, SE France). The final objective is to document the reservoir feeding and the possible leakages through overlying series. The CO2 reservoir is hosted within a horst controlled by a N-S fault network.
From the Triassic to Eocene, the Montmiral area was part of the South-East Basin of France. This period is marked by the Tethysian extension phase (Triassic-Cretaceous) followed by the closure of the basin which culminated during the Pyrenean compressive phase (Eocene). Then, from the late Eocene, the Valence Basin was individualised in particular during the Oligocene E-W rifting affecting the West of Europe. Finally the eastern border of the Basin was overthrusted by Mesozoic formations during the Alpine orogenesis (Miocene).
The Montmiral CO2 reservoir is intersected by the currently productive V.Mo.2 well, drilled through Miocene to Triassic sedimentary formations, and reaching the Palaeozoic substratum at a depth of 2771 meters. The CO2 is trapped below a depth of 2340 meters, at the base of sandy, evaporitic and calcareous formations (2340-2771m), Triassic to Sinemurian in age. These units are overlain by a 575 m-thick Domerian to Oxfordian marly sequence which seals the CO2 reservoir. Above these marls, calcareous strata (1792-1095 m), Oxfordian to Cretaceous in age, and sandy clayey formations (1095-0 m), Oligocene and Miocene in age, are deposited. The various stratigraphic levels from the Miocene to the basement were cored over a total length of ~100m.
From bottom to top, three lithological units, which exhibit well characterised contrasted diagenetic evolution, record various stages and effects of the CO2 migration:
- Lower unit: Palaeozoic metamorphic basement;
- Middle unit: Triassic-Liassic reservoir;
- Upper unit: late Jurassic to Cretaceous.
The middle unit (reservoir) and the upper unit are separated by the thick, tight seal, Domerian to Oxfordian in age.
The definition of these lithological units was made using combined petrographic techniques (cathodoluminescence CL, fluorescence, Raman spectroscopy, crushing tests), geochemical techniques (C and O isotopes) and microthermometry.
Lower unit: Paleozoïc basement - In the metamorphic basement, aquo-carbonic and CO2-dominant fluids are trapped as primary fluid inclusions in hydrothermal barite and fluoroapatite, and as secondary fluid inclusions in extensionnal microcracks crosscutting metamorphic quartz. All these fluids, trapped in the two-phase stability field, indicate firstly a limited phase separation at 300°C and 400-500 bars evolving toward wider CO2-H2O unmixing at 200°C and 200 bars. Basinal saline brines (10 and 15-25 wt % eq. NaCl and 70
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