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Titel |
Stress and Temperature Dependence of Calcite Twinning: New Experimental and Field Constraints |
VerfasserIn |
E. Rybacki, C. Janssen, G. Dresen, B. Evans |
Konferenz |
EGU General Assembly 2009
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Medientyp |
Artikel
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Sprache |
Englisch
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Digitales Dokument |
PDF |
Erschienen |
In: GRA - Volume 11 (2009) |
Datensatznummer |
250027109
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Zusammenfassung |
In low-grade metamorphic terrains at temperatures < 300Ë C e-twinning of calcite is
common. The amount and width of e-twins have been suggested to indicate stress and
temperature representing robust paleopiezometers and geothermometers.
To evaluate the stress- and temperature dependence of e-twins in calcite we have
performed a series of deformation experiments on specimens of Carrara marble in
the semibrittle field. 14 experiments were performed at 100-400 MPa confining
pressure and T < 350Ë C in a Paterson-type gas deformation apparatus. 7 samples
were deformed in axial compression test at strain rates from 10-4 -10-6s-1. 7
samples were deformed in torsion tests to shear strains γg 1.8. After testing, thin
sections of all samples were prepared for optical inspection of twin density and twin
width.
Calculations of shear stress based on the percentage of twinned grains (Jamison and
Spang, 1976) significantly underestimate the applied stress, whereas below 170 MPa the twin
density piezometer suggested by Rowe and Rutter (1990) yields too high stresses. Based on
measured twin density (between -10 and 800 twins/mm at stresses up to 450 MPa) we
propose an empirical paleopiezometer for which the square root of twin density
increases linearly with applied stress. This correlation is likely associated with
the development of dislocation cells in response to twin nucleation and growth.
The piezometer is independent of strain for γ < 1.8 at temperatures up to 350Ë
C.
To infer paleotemperature from the width and morphology of twins (Burkhard, 1993;
Ferrill et al., 2004) we also measured twin width using a U-stage. Preliminary results show
that the amount of thin twins (-¤ 1 μm) decreases continuously with increasing
temperature, whereas thick twins (> 1 μm) increases with temperature. This may indicate
that strain incompatibility at grain boundaries is less for high temperature and low
strain rate, respectively. The experimentally deformed samples were compared to
naturally-deformed low-grade calcite rocks from different fault zones. From optical thin
sections of 20 samples, deformation temperatures were estimated based on twin
width and compared to other geothermometers (fluid inclusion analysis, vitrinite
reflection, conodont colour alteration index). The data indicate a good correlation
for peak temperature conditions, but considerable scatter below about 250Ë C. |
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