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Titel Distribution of 230Thxs and 231Paxs in sediment particle classes of opal-rich and carbonate-rich sediments
VerfasserIn S. Kretschmer, S. Kusch, W. Geibert, M. Rutgers van der Loeff, G. Mollenhauer
Konferenz EGU General Assembly 2009
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 11 (2009)
Datensatznummer 250026367
 
Zusammenfassung
In many paleoceanographic studies 230Thexcess-normalization and the 231Paexcess/230Thexcess-ratio are used as tools for reconstruction of particle fluxes and ocean circulation. 230Thxs and 231Paxs analyses are usually performed on bulk sediment samples. However, it is conceivable that these two particle-reactive radioisotopes are not equally distributed between the sedimentary components of bulk sediments, because Th and Pa show preferential adsorption to specific particle types (e.g. Geibert and Usbeck, 2004). This is particularly relevant for opal-rich sediments. Lateral transport during particle settling exerts a sorting effect on particles according to different grain size classes and sinking velocities, thus affecting the sedimentary isotopesignal as well. This process may affect the applicability of 231Paxs and 230Thxs as particle flux tracers. Currently discussed problems such as apparently high focusing factors in the Panama Basin, or the applicability of 231Paxs/230Thxs-ratios for the reconstruction of ocean circulation patterns might be related to this particle sorting effect. For this study we performed particle size specific analyses of 230Thxs and 231Paxs on deep sea sediment samples from contrasting sedimentary settings, including the subtropical Atlantic Ocean (Walvis Ridge), the Southern Ocean and the tropical Pacific Ocean (Panama Basin). Bulk sediments were split into distinct particle size and density classes by sieving and settling. In opal-rich and carbonate-rich sediment, most of the 230Thxs is bound within the particle size class