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Titel CO2 isotope analysis of air samples in the upper troposphere-lowermost stratosphere region, the project CARIBIC
VerfasserIn S. S. Assonov, C. A. M. Brenninkmeijer, C. Koeppel, T. Schuck, A. Zahn, P. Taylor
Konferenz EGU General Assembly 2009
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 11 (2009)
Datensatznummer 250024272
 
Zusammenfassung
The project CARIBIC (http://caribic-atmospheric.com), aims to study atmospheric chemistry and composition by measuring many compounds and species in the upper troposphere-lowermost stratosphere (UT/LMS) around the globe by using a commercial aircraft. CARIBIC has two phases, CARIBIC-1 and CARIBIC-2 (CARIBIC-LUFTHANSA). During CARIBIC-1 (flights from Germany to mainly India, South Africa and the Caribbean), CO2 isotope composition was measured on cryogenic extracts from large air samples of 250 l STP. CO2 isotope analysis in the UT/LMS and free troposphere is continued by CARIBIC-LUFTHANSA. The new instrument container of CARIBIC-LUFTHANSA operates onboard a Lufthansa A340-600 (Frankfurt, Germany) with monthly flights from Frankfurt to remote destinations, collecting 28 air samples for laboratory analyses. A new CO2 extraction line was installed at JRC-IRMM (Geel, Belgium) and high quality isotope measurements started in June 2007. Particular focus is on traceable calibration to the VPDB-CO2 scale as well as on the quality of d18O(CO2) data, which give important information about CO2 exchange with oceans, soils and biosphere. d18O(CO2) is discussed to be a long-term indicator of global changes in the CO2 cycle as well as oceans’ feedback. About 500 air samples analysed from June 2007 to January 2009 give a reliable data set for free troposphere and the UT/LMS region. New data obtained, trends and tracer-tracer correlations will be presented at the meeting.