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Titel In-situ Down Hole Gas Measurements During Geological Storage of CO2 at Ketzin, Germany
VerfasserIn M. Zimmer, J. Erzinger, Chr. Kujawa, CO2-SINK Group
Konferenz EGU General Assembly 2009
Medientyp Artikel
Sprache Englisch
Digitales Dokument PDF
Erschienen In: GRA - Volume 11 (2009)
Datensatznummer 250023421
 
Zusammenfassung
The continuous investigation and direct determination of the gas composition in the storage horizon during and after the injection of CO2 is needed to understand the behaviour of CO2, to trace the fate of the injected gas and to critical test the geological field models. Therefore, we developed and applied a new, innovative geochemical monitoring tool for the real time and in-situ determination of CO2 and other gases in the underground and in bore holes. The method uses a phase separating silicone membrane, permeable for gases, in order to extract gases dissolved in borehole fluids, water and brines. Argon is used as a carrier gas to conduct the collected gases through capillaries to the surface. Here, the gas phase is analyzed in real-time with a portable mass spectrometer for all permanent gases. In addition, gas samples were collected for more detailed investigations in the laboratory. Down hole extraction and on-line determination of gases dissolved in brines using this gas membrane sensor technique was successful applied at the scientific CO2 storage test site in Ketzin, Germany. The dissolved CO2-concentration in the natural formation water at depth was quantified and changes in the reservoir gas concentrations of helium, hydrogen, methane and nitrogen during CO2 injection were continuously monitored. The arrival of injected krypton tracer gas at the observation well was detected and changes in hydraulic pressure and temperature were recorded. The breakthrough of CO2 into the observation well, in 50m distance, was observed after the injection of 531.5t CO2.