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Titel Technical Note: Assessing a 24/7 solution for monitoring water quality loads in small river catchments
VerfasserIn P. Jordan, R. Cassidy
Medientyp Artikel
Sprache Englisch
ISSN 1027-5606
Digitales Dokument URL
Erschienen In: Hydrology and Earth System Sciences ; 15, no. 10 ; Nr. 15, no. 10 (2011-10-11), S.3093-3100
Datensatznummer 250012988
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/hess-15-3093-2011.pdf
 
Zusammenfassung
Quantifying nutrient and sediment loads in catchments is difficult owing to diffuse controls related to storm hydrology. Coarse sampling and interpolation methods are prone to very high uncertainties due to under-representation of high discharge, short duration events. Additionally, important low-flow processes such as diurnal signals linked to point source impacts are missed. Here we demonstrate a solution based on a time-integrated approach to sampling with a standard 24 bottle autosampler configured to take a sample every 7 h over a week according to a Plynlimon design. This is evaluated with a number of other sampling strategies using a two-year dataset of sub-hourly discharge and phosphorus concentration data. The 24/7 solution is shown to be among the least uncertain in estimating load (inter-quartile range: 96% to 110% of actual load in year 1 and 97% to 104% in year 2) due to the increased frequency raising the probability of sampling storm events and point source signals. The 24/7 solution would appear to be most parsimonious in terms of data coverage and certainty, process signal representation, potential laboratory commitment, technology requirements and the ability to be widely deployed in complex catchments.
 
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