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Titel Increasing silicon concentrations in Bohemian Forest lakes
VerfasserIn J. Vesely, V. Majer, J. Kopáček, J. Safanda, S. A. Norton
Medientyp Artikel
Sprache Englisch
ISSN 1027-5606
Digitales Dokument URL
Erschienen In: Hydrology and Earth System Sciences ; 9, no. 6 ; Nr. 9, no. 6 (2005-12-31), S.699-706
Datensatznummer 250007149
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/hess-9-699-2005.pdf
 
Zusammenfassung
Long-term trends of dissolved silicon (Si) concentrations in five glacial lakes in the Bohemian Forest, Czech Republic, recovering from acidification show higher mobility of Si from the soil to surface waters despite lower atmospheric deposition of acids. Si increased by 0.95 to 1.95 µmol yr-1 (36 to 51%) from 1986-2004 and with increasing pH. A change in soil solution conditions because of a sharp decrease in acidic deposition has led to marked decline in Al mobility and to considerable decreases in dissolved Al, especially Al3+. The increase in Si may be related to: (1) unblocking of the inhibitory effect of dissolved Al on weathering of aluminosilicates, (2) biogenic opal (phytoliths) dissolving faster, and/or (3) lower Si precipitation as secondary aluminosilicates in soil. The change in Al speciation on the dissolution rate of biogenic silica is critical. A lack of change in Si at sites outside central Europe may be explained by small or no decline in mobility of dissolved Al. The effect of a long-term increase in temperature was probably minor.
 
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