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Titel Dimethylamine and ammonia measurements with ion chromatography during the CLOUD4 campaign
VerfasserIn A. P. Praplan, F. Bianchi, J. Dommen, U. Baltensperger
Medientyp Artikel
Sprache Englisch
ISSN 1867-1381
Digitales Dokument URL
Erschienen In: Atmospheric Measurement Techniques ; 5, no. 9 ; Nr. 5, no. 9 (2012-09-07), S.2161-2167
Datensatznummer 250003083
Publikation (Nr.) Volltext-Dokument vorhandencopernicus.org/amt-5-2161-2012.pdf
 
Zusammenfassung
The CLOUD project investigates the influence of galactic cosmic rays on the nucleation of new particles in an environmental chamber at CERN. Dimethylamine (DMA) was injected intentionally into the CLOUD chamber to reach atmospherically relevant levels away from sources (up to 100 pptv) in order to study its effect on nucleation with sulphuric acid and water at 278 K. Quantification of DMA and also background ammonia (NH3) was performed with ion chromatography (IC). The IC method used together with the sampling line developed for CLOUD in order to measure NH3 and DMA at low pptv levels is described; the overall sampling efficiency of the method is discussed; and, finally, mixing ratios of NH3 and DMA measured during CLOUD4 are reported.
 
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